Residential - Blog

May 2020
Hard Water Facts

What is Hard Water?

Hard Water is water that contains a high mineral content such as an amount of dissolved calcium and magnesium in the water.

 

Water hardness can present in two ways:

 

  • Temporary hardness is due to the bicarbonate ion, HCO3-, being present in the water. This type of hardness can be removed by boiling the water to expel the CO2, as indicated by the following equation: 

Ca(HCO3)2 →← CaCO3 + CO2 + H2O

 

  • Permanent hardness is due to calcium and magnesium nitrates, sulfates, and chlorides, etc. This type of hardness cannot be eliminated by boiling. 

 

The Scientific Definition of Hard Water

 

The scientific definition of water hardness refers to the presence of dissolved ions, mainly of calcium Ca2+ and magnesium Mg2+ which are acquired through contact with rocks and sediments in the environment. The positive electrical charges of these ions are balanced by the presence of anions (negative ions), of which bicarbonate HCO3– and carbonate CO32– are most important. These ions have their origins in limestone sediments and also from carbon dioxide which is present in all waters exposed to the atmosphere and especially in groundwater.

 

High ion concentrations do not cause any health threat, but they can engage in reactions that leave impenetrable mineral deposits. These deposits can make hard water unsuitable for many uses such as laundry, dishwashing and commercial/industrial processes. It also leaves an unwanted residue that on home water fixtures such as aerators and shower heads that are extremely difficult to remove.

 

There often varying definitions for connected to the phrase hard water. The basic component is the same - Based on all the different definitions of hard water, it comes down to water that has dissolved ionic compounds in it.

 

How do Ions get in Water? 

Understanding the following definitions will help you understand how ions get into the water, thus creating hard water. 

 

  • Dissociation is a general process in which ionic compounds separate into smaller ions, usually in a reversible manner.
  • Dissolution or dissolving is the process where ionic crystals break up into ions in water.
  • Hydration is the process where ions become surrounded by water molecules.
  • Dissolving of ions is when some substances are dissolved in water, they undergo either a physical or a chemical change that yields ions in solution.
  • Electrolytes are an important class of compounds that yield ions when dissolved. Substances that do not yield ions when dissolved are called nonelectrolytes. If the physical or chemical process that generates the ions is essentially 100% efficient (all the dissolved compound yield ions), then the substance is known as a strong electrolyte. If only a relatively small fraction of the dissolved substance undergoes the ion-producing process, it is called a weak electrolyte. Substances may be identified as strong, weak, or nonelectrolytes by measuring the electrical conductance of an aqueous solution containing the substance. To conduct electricity, a substance must contain freely mobile, charged entities. Most familiar is the conduction of electricity through metallic wires, in which case the mobile, charged entities are electrons. Solutions may also conduct electricity if they contain dissolved ions, with conductivity increasing as ion concentration increases.

 

Water and other polar molecules are attracted to ions, as shown in the electrostatic attraction between an ion and a molecule with a dipole that is called an ion-dipole attraction. These attractions play an important role in the dissolution of ionic compounds in water.

When ionic compounds dissolve in water, the ions will separate and disperse uniformly throughout the solution because water molecules surround and solvate the ions, reducing the strong electrostatic forces between them. This process represents a physical change known as dissociation. Under most conditions, ionic compounds will dissociate nearly completely when dissolved, and so they are classified as strong electrolytes.

In other cases, the electrostatic attractions between the ions in a crystal are so large, or the ion-dipole attractive forces between the ions and water molecules are so weak, that the increase in disorder cannot compensate for the energy required to separate the ions, and the crystal is insoluble. Such is the case for compounds such as calcium carbonate (limestone), calcium phosphate (the inorganic component of bone), and iron oxide (rust).

Electrolytes are one of the main reasons why hard water is healthy for you. Science has proven that electrolytes play an important role in our health. If you deplete your electrolytes the adverse effects can be any of the following:

 

  • irregular heartbeat
  • fast heart rate
  • fatigue
  • lethargy
  • convulsions or seizures
  • nausea
  • vomiting
  • diarrhea or constipation
  • abdominal cramping
  • muscle cramping
  • muscle weakness
  • irritability
  • confusion
  • headaches
  • numbness and tingling

 

Having said all that, electrolytes are minerals that carry an electrical charge when dissolved in water.

 

How Hard is Your Water?

Now that ions are in the water and hard water has formed, we can now measure the water hardness.

 

According to the USGS, the hardness of water is determined based on the concentration of dissolved calcium and magnesium in ppm (parts per million), mg/L (milligrams per liter), or GPG (grains per gallon)[17.1 ppm or mg/L = 1 gpg]

  • soft water - 0 to 60 mg/L (milligrams per liter) 
  • moderately hard water - 61 to 120 mg/L (milligrams per liter) 
  • hard water - 121 to 180 mg/L (milligrams per liter) 
  • very hard water - more than 180 mg/L (milligrams per liter) 

 

For specific hard water numbers, you can visit www.hydroflow-usa.com/water-hardness-map

 

Hard Water and the Precipitation of Calcium Carbonate

The next important thing to understand about hard water is precipitation and how it occurs.

In chemistry, a precipitate is an insoluble solid that emerges from a liquid solution. The emergence of the insoluble solid from the solution is called precipitation. Once water is supersaturated, it contains more of the dissolved material than could be dissolved by the solvent (water) under normal circumstances.

 

When a precipitating agent is introduced, this causes the chemical reaction necessary for the insoluble compound to emerge. The most common precipitating agent is CO2 and it plays a huge role in the precipitation of calcium carbonate in water. This is the major source of scale and the root cause of hard water problems.

 

Where Does Hard Water Come From?

Hard water originates from deep in the earth in large bodies of water that are underground known as aquifers. Some of these aquifers are surrounded by limestone and other mineral deposits. Due to the high levels of dissolved CO2 in water (carbonic acid), this lowers the pH of the water causing it to become acidic.

 

Once the pH of the water drops below 7.6 it will begin to slowly dissolve the limestone and magnesium, which is how the calcium and magnesium ions end up in the water. This is the perfect recipe to produce hard water. Since CO2 is abundant and is dissolved in the water, which creates carbonic acid, along with calcium and magnesium ions, you have everything you need for precipitation of calcium carbonate. The water only needs to have its saturation point changed by pH, temperature or pressure for this to happen.

 

Is Soap Scum and Hard Water the Same Thing?

No, they’re not the same thing but there is a relationship between them. With hard water, soap solutions form a white precipitate known as soap scum, which reduces lathering ability. This should not be confused with calcium carbonate that hard water precipitates when there is a change in temperature, pH or pressure. The reason soap scum forms is that the 2+ ions destroy the surfactant properties of the soap by forming a solid precipitate (the soap scum). A major component of such scum is calcium stearate, which arises from sodium stearate, the main component of soap:

2 C17H35COONa+ + Ca2+ → (C17H35COO)2Ca + 2 Na+

 

Hardness can thus be further defined as a characteristic property of water that reduces the lathering of soap. 

 

How to Make Your Own Batch of Hard Water

Before creating your own batch of hard water, it’s important to understand what is referred to as the “Calcium Cycle”.

 

The calcium cycle is a transfer of calcium between dissolved and solid phases. This ensures a continuous supply of calcium ions into waterways from rocks, organisms, and soils.

 

The calcium cycle starts when rainwater reacts with carbon dioxide in the air, thus producing carbonic acid. The carbonic acid in the rainwater reacts with the calcium carbonate in rock formations like limestone, dolomite, gypsum, and other rocks containing calcium carbonate, which is causing calcium bicarbonate (calcium hydrogen carbonate) to form. Calcium bicarbonate is carried to the ocean through runoff. Many of the ocean’s calcium ions are consumed and removed from aqueous environments when organisms use the calcium bicarbonate to form shells and skeletal structures. When these organisms die, they become incorporated into layers on the ocean seabeds. Over time, due to geological movements and pressure, these layers form limestone and other calcium-rich rock formations, thereby completing the calcium cycle.

 

 

Directions to Create Hard Water Similar to How it is Created in Nature

This recipe is closest to what you would find in nature. Two important things to note when creating your own hard water.

 

  • First, use distilled water which has sufficient room for ions to be introduced before supersaturation occurs, or a sufficiently high saturation point to accept those ions.
  • Second, it’s important to keep the water very cold because the solubility of calcium will decrease as the water temperature rises.

Materials:

  • 10-gallon aquarium
  • 10 gallons of distilled water
  • CO2 tank with regulator and aerator line attachment
  • Limestone
  • Dolomite
  • 3 dozen eggshells washed and sanitized
  • 300 grams of calcium chloride
  • 300 grams of Epsom Salt (magnesium sulfate)

 

Directions:

  1. Fill a 10-gallon Aquarium with distilled water and run the aerator line back and forth across the bottom.
  2. Cover the bottom layer, including the aerator, with limestone.
  3. Add a layer of crushed eggshells (sanitized), the layer of dolomite, and a second layer of limestone.
  4. Connect a carbon dioxide (CO2) tank with regulator to your aerator line. 
  5. Bubble CO2 continuously through the layers until you achieve the water hardness levels you desire, by measuring with a water hardness meter.
    1. Every time the water pH goes below 7.6 the calcium media will begin to dissolve to counteract the CO2 that’s causing the water to become acidic. This process releases calcium ions (Ca2+ ) directly into the water. At the same time, the CO2 is combining with the water to create carbonic acid, which dissociates into hydrogen ions (H+) and bicarbonate ions (HCO3-). 
    2. Magnesium is soluble in water so you should wait to add the magnesium into your water until at least 150 PPM of calcium hardness is reached through the CO2 bubbler action.
  6. Add 300 grams of Epsom Salt (magnesium sulfate) into the aquarium. This will add the necessary magnesium ions into the water.
  7. Finally, add 300 grams of calcium chloride to create your permanent hardness.

 

This setup attempts to emulate the calcium cycle described above. The calcium cycle is a common thread between terrestrial, marine, geological, and biological processes. Calcium moves through these different media as it cycles throughout the Earth. The marine calcium cycle is influenced by changing atmospheric carbon dioxide due to ocean acidification. 

 

 

Directions to Create Hard Water in a Lab (Fast Method)

 

Materials:

  • 60 grams of Calcium Hydroxide
  • 10-gallon fish tank filled with distilled water
  • CO2 tank with regulator and aerator line attachment (example)
  • 300 grams of calcium chloride
  • 300 grams of Epsom Salt

 

Directions

  1. Add 60 grams of calcium hydroxide to the 10 gallons of distilled water. 
  2. Stir until the water goes clear (It’s ok if it doesn’t all dissolve). 
  3. Once the water is clear, run the CO2 with the attached aerator line along the bottom of the tank. 
  4. Turn on the CO2 tank. Adjust the regulator so the flow of CO2 is steady but not causing turbulence in the water.
  5. The water will instantly turn milky when the CO2 is introduced into the water.
  6. Continue to bubble CO2 through the water until it goes clear again. 
  7. Once it’s clear, turn off the CO2.
  8. Add 300 grams of Epsom Salt (magnesium sulfate).
  9. Add 300 grams of calcium chloride to the water. To remove the solids left over, run the water through a double-lined coffee filter. You should have a clear water solution that will test with a high level of dissolved calcium in it.